Determination of Sulfide Based on Hydrogen Peroxide-morin Chemiluminescence System

YANG Ying-chun; FENG Yuan-yuan; YIN Hong-ling; YE Zhi-xiang; YU Jing; YANG Huai-jin

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Determination of Sulfide Based on Hydrogen Peroxide-morin Chemiluminescence System

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- Determination of Sulfide Based on Hydrogen Peroxide-morin Chemiluminescence System
- Chinese Journal of Luminescence Vol. 32, Issue 2, Pages: 194-199(2011)
- 作者机构：
  
  成都信息工程学院资源环境系,四川成都,610225
- 作者简介：
- 基金信息：
- DOI：
  CLC： O657.3;O482.31
- Received：06 July 2010，
  
  Revised：05 September 2010，
  
  Published：2011
- 稿件说明：
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杨迎春, 冯媛媛, 印红玲, 叶芝祥, 余静, 杨怀金. 基于过氧化氢-桑色素化学发光体系的硫化物检测[J]. 发光学报, 2011,32(2): 194-199

YANG Ying-chun, FENG Yuan-yuan, YIN Hong-ling, YE Zhi-xiang, YU Jing, YANG Huai-jin. Determination of Sulfide Based on Hydrogen Peroxide-morin Chemiluminescence System[J]. Chinese Journal of Luminescence, 2011,32(2): 194-199
杨迎春, 冯媛媛, 印红玲, 叶芝祥, 余静, 杨怀金. 基于过氧化氢-桑色素化学发光体系的硫化物检测[J]. 发光学报, 2011,32(2): 194-199 DOI：

YANG Ying-chun, FENG Yuan-yuan, YIN Hong-ling, YE Zhi-xiang, YU Jing, YANG Huai-jin. Determination of Sulfide Based on Hydrogen Peroxide-morin Chemiluminescence System[J]. Chinese Journal of Luminescence, 2011,32(2): 194-199 DOI：

摘要

在pH=9~10范围内

过氧化氢与桑色素溶液混合后可产生较弱的化学发光

表面活性剂十六烷基三甲基溴化铵(CTMAB)和S

对该体系化学发光有较强的增敏作用

据此建立了H

-桑色素-CTMAB化学发光体系测定S

的新方法

并对该体系的化学发光反应机理进行了研究。在最佳的实验条件下

在(0.9~9.0)10

-8

g/mL质量浓度范围内与化学发光强度增加值呈良好的线性关系

线性方程为

=49.41+3.361 2

Abstract

In alkaline condition(pH=9~10)

a weak chemiluminescence signal was produced when H

was injected into morin solution

and the chemiluminescence signal could be greatly enhanced after the introduction of cetyl trimethyl ammonium bromide(CTMAB) and sulfide. Based on the observation

-morin-CTMAB chemiluminescence system has been developed for the determination of sulfide. The possible mechanism of chemiluminescence reaction has also been discussed. Under the optimized conditions

the chemiluminescence intensity of the system presented a linear relationship with the concentration of sulfide in the range of (0.9~9.0)10

-8

g/mL

the linear dynamic equation was

=49.41+3.3612

with correlation coefficient of 0.999 0. The detection limit (S/N=3) was 1.210

-9

g/mL. The relative standard deviations(RSD) was 2.5％ for 8.010

-8

g/mL sulfide solution. The proposed method was successfully applied to the determination of sulfide in environmental water samples with recoveries in the range of 95.5%~101.3%.

关键词

Keywords

references

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