Fabrication and Luminescence Properties of Zn2SiO4(ZnB2O4) ∶ Mn2+ ,Sm3+ Phosphors

ZHANG Zhi-wei; ZHANG Wei-guo; Niu Shao-li

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Fabrication and Luminescence Properties of Zn₂SiO₄(ZnB₂O₄) ∶ Mn²⁺ ,Sm³⁺ Phosphors

paper | 更新时间：2020-08-12

- Fabrication and Luminescence Properties of Zn₂SiO₄(ZnB₂O₄) ∶ Mn²⁺ ,Sm³⁺ Phosphors
- Chinese Journal of Luminescence Vol. 32, Issue 2, Pages: 144-148(2011)
- 作者机构：
  
  河北科技师范学院,河北秦皇岛,066600
- 作者简介：
- 基金信息：
- DOI：
  CLC： O482.31
- Received：23 August 2010，
  
  Revised：15 October 2010，
  
  Published Online：22 February 2011，
  
  Published：22 February 2011
- 稿件说明：
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张志伟, 张卫国, 牛少莉. Zn2SiO4∶Mn2+, Sm3+发光材料的制备与荧光性能[J]. 发光学报, 2011,32(2): 144-148

ZHANG Zhi-wei, ZHANG Wei-guo, Niu Shao-li. Fabrication and Luminescence Properties of Zn2SiO4(ZnB2O4) ∶ Mn2+ ,Sm3+ Phosphors[J]. Chinese Journal of Luminescence, 2011,32(2): 144-148
张志伟, 张卫国, 牛少莉. Zn2SiO4∶Mn2+, Sm3+发光材料的制备与荧光性能[J]. 发光学报, 2011,32(2): 144-148 DOI：

ZHANG Zhi-wei, ZHANG Wei-guo, Niu Shao-li. Fabrication and Luminescence Properties of Zn2SiO4(ZnB2O4) ∶ Mn2+ ,Sm3+ Phosphors[J]. Chinese Journal of Luminescence, 2011,32(2): 144-148 DOI：

摘要

使用高温固相法首次合成了Zn

SiO

(ZnB

) ∶ Mn

发光材料

探讨了烧结温度、Sm

含量对样品荧光性能的影响。利用X射线衍射(XRD)、荧光光谱等分析手段对Zn

SiO

(ZnB

) ∶ Mn

粉末的结构、发光性能进行了表征。确定了该荧光材料的最佳合成条件

离子掺杂浓度等。实验结果表明:组成为Zn

SiO

(ZnB

) ∶ 1.2%Mn

8%Sm

的样品在950 ℃还原气氛下烧结

发光强度最高;反应生成的ZnB

和掺杂Sm

可以大幅提高材料发光强度。

Abstract

SiO

(ZnB

) ∶ Mn

phosphors was fabricated by solid reaction method. The influences of sintered temperature and Sm

content on the luminescence properties of Zn

SiO

(ZnB

) ∶ Mn

phosphors were studied. Powder structure and luminescence properties were characterized by means of XRD

excitation and emission spectra. The experimental results indicate that Zn

SiO

(ZnB

) ∶ Mn

has two excitation peaks at 220 nm and 250 nm

the luminescence intensity is the largest when the sintered temperature is at 950 ℃ in reducing atmosphere

and the emission peaks at 521 nm. The ZnB

as a part of host produced in the reaction can improve the luminescence intensity. At 950 ℃

there are most ZnB

reaction products

meanwhile

ZnB

has the best crystalline properties. With the Sm

content increased

the phase is not changed

however

to a large extent

the luminescence intensity can be improved. When the Sm

mole fraction is 8%

the intensity is the most and 5 times stronger than that for 4% Sm

. With the increasing of Sm

mole fraction

the luminescence emission peak has blue-shift from 540 nm to 521 nm.

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Keywords

references

Seoa K I, Parka J H, Kima J S, et al. Highly efficient transparent Zn2SiO4 ∶ Mn2+ phosphor film on quartz glass [J]. J. Lumin., 2009, 129 (7):715-719.[2] Wang Lili, Liu Xiaoming, Hou Zhiyao, et al. Electrospinning synthesis and luminescence properties of one-dimensional Zn2SiO4 ∶ Mn2+ microfibers and microbelts [J]. J. Phys. Chem. C, 2008, 112 (48):18882-18888.[3] Diao Chienchen, Yang Chengfu. Synthesis of high efficiency Zn2SiO4 ∶ Mn2+ green phosphors using nano-particles [J]. Ceramics International, 2010, 36 (5):1653-1657.[4] Jiang Yaqi, Chen Jie, Xie Zhaoxiong, et al. Syntheses and optical properties of - and -Zn2SiO4 ∶ Mn nanoparticles by solvothermal method in ethylene glycol-water system [J]. Materials Chemistry and Physics, 2010, 120 (2-3):313-318.[5] Alavi S, Dexpert-Ghys J, Caussat B. High temperature annealing of micrometric Zn2SiO4 ∶ Mn phosphor powders in flui-dized bed [J]. Materials Research Bulletin, 2008, 43 (10):2751-2762.[6] Park J H, Park K W, Lee J B, et al. Excellent brightness with shortening lifetime of textured Zn2SiO4 ∶ Mn2+ phosphor films on quartz glass [J]. Jpn. J. Appl. Phys., 2010, 49 (4):42603-42607.[7] Lee D H, Wang W, Gutu T, et al. Biogenic silica based Zn2SiO4 ∶ Mn2+ and Y2SiO5 ∶ Eu3+ phosphor layers patterned by inkjet printing process [J]. J. Mater. Chem., 2008, 18 (31):3633-3635.[8] Xu G Q, Xu H T, Zheng Z X, et al. Preparation and characterization of Zn2SiO4 ∶ Mn phosphors with hydrothermal methods [J]. J. Lumin., 2010, 130 (10):1717-1720.[9] Hao Yan, Wang Yuhua, Zhang Zhanhui et al. Preparation and photoluminescence of Zn2SiO4 ∶ Mn2+ phosphor by combustion technique [J]. Chin. J. Lumin.(发光学报), 2004, 25 (4):441-445 (in Chinese).[10] You Hongpeng, Hong Guangyan, Zeng Xiaoqing. VUV and UV spectral properties of Zn2SiO4 ∶ Mn [J]. Chin. J. Lumin.(发光学报), 2000, 21 (4):349-352 (in Chinese).[11] Zhang Maisheng, Qi Jiaxiong, Yang Yansheng. Synthesis of photophosphor Zn2SiO4 ∶ Mn2+ , Er3+ with subnanometer size by sol-gel and microwave radiation methods [J]. Chin. J. Lumin.(发光学报), 1999, 20 (3):258-261 (in Chinese).[12] Lei Bingfu, L Yeliang, Ye Zeren et al. Long-lasting properties of Zn2SiO4 ∶ Mn, Cd phosphor [J]. Chin. J. Lumin. (发光学报), 2005, 26 (1):67-71 (in Chinese).[13] Li J, Zhang C X, Tang Q, et al. Synthesis, photoluminescence, thermoluminescence and dosimetry properties of novel phosphor Zn(BO2)2 ∶ Tb [J]. Journal of Physics and Chemistry of Solids, 2007, 68 (2):143-147.[14] Liu W R, Lin C C, Chiu Y C, et al. ZnB2O4 ∶ Bi3+ ,Eu3+:a highly efficient, red-emitting phosphor [J]. Optics Express, 2010, 18 (3):2946-2951.[15] Wu Qiaoli, Zhang Na, Yang Qianshe, et al. Effect of H3BO3 as flux on the properties of Zn2SiO4 ∶ Mn green phosphor [J]. J. Chin. Ceramic Society (硅酸盐学报), 2008, 36 (11):1660-1663 (in Chinese).[16] Parmar M C, Zhuang W D, Murthy K V R, et al. Role of SiO2 in Zn2SiO4 ∶ Mn2+ phosphor used in optoelectronic materials [J]. Indian J. of Engineering and Materials Sciences, 2009, 16 :185-187.[17] Zhang Q H, Wang J, Zhang M, et al.Luminescence properties of Sm3+ doped Bi2ZnB2O7 [J]. J. Rare Earths, 2006, 24 (4):392-395.[18] Neeraj S, Kijima N, Cheetham A K. Novel red phosphors for solid-state lighting:the system BixLn1-xVO4 ∶ Eu3+ ／Sm3+(Ln=Y, Gd) [J]. Solid State Commun. Phys., 2004, 131 (1):65-69.[19] Liu F S, Liu Q L, Liang J K, et al. Optical spectra of Ln3+(Nd3+ ,Sm3+ ,Dy3+ ,Ho3+ ,Er3+)-doped Y3GaO6[J].J. Lumin., 2005, 111 (1):61-68.

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