Fluorescence Polarization and Time Resolved Characteristics of Isopropanol-water Mixture

HAN Cai-qin; DUAN Pei-tong; WU Bin; LIU Ying; LUO Xiao-sen; NI Xiao-wu

doi:null

您当前的位置：

首页 >

文章列表页 >

Fluorescence Polarization and Time Resolved Characteristics of Isopropanol-water Mixture

paper | 更新时间：2020-08-12

- Fluorescence Polarization and Time Resolved Characteristics of Isopropanol-water Mixture
- Chinese Journal of Luminescence Vol. 32, Issue 12, Pages: 1303-1307(2011)
- 作者机构：
  
  1. 南京理工大学理学院,江苏南京,210094
  2. 徐州师范大学物理与电子工程学院,江苏徐州,221116
- 作者简介：
- 基金信息：
- DOI：
  CLC： O433.4
- Received：03 September 2011，
  
  Revised：18 October 2011，
  
  Published Online：22 December 2011，
  
  Published：22 December 2011
- 稿件说明：
移动端阅览
韩彩芹, 段培同, 吴斌, 刘莹, 骆晓森, 倪晓武. 异丙醇-水配合液的荧光偏振和时间分辨特性[J]. 发光学报, 2011,32(12): 1303-1307

HAN Cai-qin, DUAN Pei-tong, WU Bin, LIU Ying, LUO Xiao-sen, NI Xiao-wu. Fluorescence Polarization and Time Resolved Characteristics of Isopropanol-water Mixture[J]. Chinese Journal of Luminescence, 2011,32(12): 1303-1307
韩彩芹, 段培同, 吴斌, 刘莹, 骆晓森, 倪晓武. 异丙醇-水配合液的荧光偏振和时间分辨特性[J]. 发光学报, 2011,32(12): 1303-1307 DOI：

HAN Cai-qin, DUAN Pei-tong, WU Bin, LIU Ying, LUO Xiao-sen, NI Xiao-wu. Fluorescence Polarization and Time Resolved Characteristics of Isopropanol-water Mixture[J]. Chinese Journal of Luminescence, 2011,32(12): 1303-1307 DOI：

摘要

研究了紫外光照射下异丙醇-水配合液的偏振荧光光谱

以及不同荧光峰处光子强度随时间的衰变过程

计算了偏振度并讨论了其偏振特性

测试了不同峰位对应的荧光寿命并分析了其荧光发射特性。结果表明

异丙醇-水配合液在紫外光激励下发射的荧光为具有确定分子取向的部分偏振光

偏振度和各向异性度分别为0.542和0.441。在波长为220 nm和232 nm的激发光照射下

荧光峰位于277

284

293

309 nm

对应寿命均约为17 ns。而328

345

362 nm荧光峰对应的平均寿命分别约为21

16 ns

这与氢键作用下异丙醇和水形成团簇结构的相对稳定性有关。

Abstract

The polarization fluorescence spectra of isopropanol-water mixture excited by ultraviolet light was studied experimentally. The decay process of fluorescence intensity was detected at different center emission peaks. The curve was fitted by an exponential function and the processing data was obtained by deconvolution. Both the polarization degree and fluorescence lifetime were calculated

and mathematical characterization was performed for the fluorescence counts decay curves. The fluorescence emission and polarization characteristics were discussed. It is found that the isopropanol-water mixture excited by ultraviolet light obtains partially polarized fluorescence with certain molecular orientation. The polarization degree and anisotropy degree are 0.542 and 0.441

respectively. Induced by exciting light with wavelengths of 220 nm and 232 nm

the fluorescence lifetime of isopropanol-water mixture at peaks of 277

284

293

309 nm is about 17 ns. While the average fluorescence lifetime at peaks of 328 nm

345 nm and 362 nm is around 21

16 ns

respectively. It is related with the molecular cluster structure relative stability of isopropanol-water mixture by the action of hydrogen bond. The research will contribute to the study of the molecular characteristic of isopropanol-water cluster.

关键词

Keywords

references

Smyk B, Amarowicz R, Szabelski M, et al. Steady-state and time-resolved fluorescence studies of stripped borage oil [J]. Analytica Chimica Acta, 2009, 646 (7):85-89.[2] Liu B S, Xue C L, Wang J, et al. Studies on the interaction between ciprofloxacin and ofloxacin in presence of bovine serum albumin by spectroscopic methods [J]. Chin. J. Lumin. (发光学报), 2010, 31 (2):285-290 (in Chinese).[3] Nevin A, Comelli D, Valentini G, et al. Time-resolved fluorescence spectroscopy and imaging of proteinaceous binders used in paintings [J]. Anal Bioanal Chem, 2007, 388 (8):1897-1905.[4] Gao X X, Mou J, Wang W J, et al. Influence of UV illumination on fluorescence spectrum properties of azobenzen [J]. Chin. J. Lumin. (发光学报), 2009, 30 (4):549-553 (in Chinese).[5] Pei L S, Zhang J, Kong W, et al. Polarization spectroscopy of aluminum phthalocyanine hydroxide embedded in superfluid helium droplets [J]. Chem. Phys. Lett., 2008, 462 (6):173-177.[6] Levitt A J, Matthews R D, Ameer-Beg M S, et al. Fluorescence lifetime and polarization-resolved imaging in cell biology[J]. Current Opinion in Biotechnology, 2009, 20 (1):28-36.[7] Pu Y, Wang W B, Achilefu S, et al. Time-resolved fluorescence polarization anisotropy and optical imaging of cybesin in cancerous and normal prostate tissues [J]. Optics Communications, 2007, 274 (1):260-267.[8] Xu J G, Wang Z B. Method of Fluorescence Analysis (Third Edition) (荧光分析法第三版) [M]. Beijing: Science Press, 2006, 184:162-167 (in Chinese).[9] Mandal A, Prakash M, Kumar R M, et al. Ab initio and DFT studies on methanol water clusters [J]. J. Phys. Chem. A, 2010, 114 (6):2250-2258.[10] Alavi S, Takeya S, Ohmura R, et al. Hydrogen-bonding alcohol-water interactions in binary ethanol, 1-propanol, and 2-propanol+methane structure II clathrate hydrates [J]. J. Chem. Phys., 2010, 133 (7):074505-1-6.[11] Xu H, Zhu T, Yu R P. Study on the absorption and fluorescence spectra of ethylene glycol and glycerol [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2007, 27 (7):1381-1384 (in Chinese).[12] Razavi S, Sabetghadam A, Mohammadi T. Dehydration of isopropanol by PVA-APTEOS/TEOS nanocomposite membranes [J]. Chemical Engineering Research and Design, 2011, 89 (2):148-155.[13] Han C Q, Duan P T, Wu B, et al. Research on cluster characteristics of isopropanol-water complex by derivative fluorometry [J]. J. Optoelectronics Laser(光电子激光), 2010, 21 (7):1097-1101 (in Chinese).[14] Herzberg G. Molecular Spectroscopy and Molecular StructureⅡ: Infrared Spectrum and Raman Spectrum of Polyatomic Molecule (分子光谱与分子结构Ⅱ: 多原子分子的红外光谱与喇曼光谱) [M]. Beijing: Science Press, 1986:230 (in Chinese).

Views

180

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress in Artificial Micro-nano Structures Enhanced Photoluminescence

Theoretical Calculation of Emission Properties of CuInS₂/ZnS Quantum Dot Fiber

Preparation and Photoluminescence Properties of CaLuBO₄: Tb³⁺ Phosphor

Preparation and Luminescence Properties of Lu₂O₃: Pr³⁺ Phosphors Codoped with Li⁺, Na⁺, K⁺, Ca²⁺, Ba²⁺ Ions

Synthesis and Luminescence Properties of Cesium Lead Bromine Quantum Dots

Related Author

DAI Ning

SHAO Yuchuan

WEN Zhengji

XU Qianqian

ZHANG Xuan

ZHAO Wenchao

Lei ZHANG

Shuai LI

Related Institution

School of Physics and Optoelectronic Engineering， Hangzhou Institute for Advanced Study， University of Chinese Academy of Sciences

Laboratory of Thin Film Optics， Shanghai Institute of Optics and Fine Mechanics， Chinese Academy of Sciences

Huzhou Key Laboratory of Urban Multidimensional Perception and Intelligent Computing

School of Electronic Information， Huzhou College

Province Key Laboratory of Superhard Materials, College of Physics and Electronic Engineering, Mudanjiang Normal University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰