Synthesis and Fluorescence Properties of Doped Europium Benzene-1 ,3 ,5-tricarboxylate Complexes

MA Rui-jun; ZHAO Yong-liang; Wuren Qimuge; LI Xin; SUN Hui-juan

doi:null

您当前的位置：

首页 >

文章列表页 >

Synthesis and Fluorescence Properties of Doped Europium Benzene-1 ,3 ,5-tricarboxylate Complexes

paper | 更新时间：2020-08-12

- Synthesis and Fluorescence Properties of Doped Europium Benzene-1 ,3 ,5-tricarboxylate Complexes
- Chinese Journal of Luminescence Vol. 31, Issue 6, Pages: 920-925(2010)
- 作者机构：
  
  1. 内蒙古大学化学化工学院,内蒙古呼和浩特,010021
  2. 北京大学稀土材料及应用重点实验室北京,100871
- 作者简介：
- 基金信息：
- DOI：
  CLC： O482.31
- Received：25 August 2009，
  
  Revised：14 October 2009，
  
  Published Online：22 November 2010，
  
  Published：22 November 2010
- 稿件说明：
移动端阅览
马瑞军, 赵永亮, 乌仁其木格, 李欣, 孙慧娟. 均苯三甲酸铕掺杂配合物的合成及其荧光性能[J]. 发光学报, 2010,31(6): 920-925

MA Rui-jun, ZHAO Yong-liang, Wuren Qimuge, LI Xin, SUN Hui-juan. Synthesis and Fluorescence Properties of Doped Europium Benzene-1 ,3 ,5-tricarboxylate Complexes[J]. Chinese Journal of Luminescence, 2010,31(6): 920-925
马瑞军, 赵永亮, 乌仁其木格, 李欣, 孙慧娟. 均苯三甲酸铕掺杂配合物的合成及其荧光性能[J]. 发光学报, 2010,31(6): 920-925 DOI：

MA Rui-jun, ZHAO Yong-liang, Wuren Qimuge, LI Xin, SUN Hui-juan. Synthesis and Fluorescence Properties of Doped Europium Benzene-1 ,3 ,5-tricarboxylate Complexes[J]. Chinese Journal of Luminescence, 2010,31(6): 920-925 DOI：

摘要

合成了两个系列的均苯三甲酸铕配合物。其一是以均苯三甲酸(H

btc)为配体

及掺杂过渡金属Zn

、Cd

、Mn

、Ni

为中心离子的配合物;其二是以均苯三甲酸、邻菲啰啉(Phen)为配体

及掺杂Y

、La

、Gd

为中心离子的异核稀土配合物。对配合物进行了元素分析、差热-热重、红外光谱、紫外光谱、荧光寿命及荧光性能等方面的测试分析。配合物的组成分别为:Eu

O(1)、Eu

1.5

O(2)、Eu

0.5

1.5

O(3)、Eu

0.5

1.5

O(4)、Eu

0.5

1.5

O(5)、EuZn

OH)

O(6)、EuCd

-(C

OH)

2.5

O(7)、EuMn

OH)

O(8)、EuNi

OH)

O(9)(其中

=btc

'=Phen)。均苯三甲酸的羧酸氧原子和邻菲啰啉的氮原子与稀土离子配位。差热-热重的测试结果表明

均苯三甲酸-邻菲啰啉异核稀土配合物的分解温度为490℃

铕掺杂过渡金属配合物分解温度为450℃

两类配合物的最终分解产物均为氧化物。荧光光谱的测试结果表明

三元配合物Eu

1.5

O(2)的荧光强度明显高于二元配合物Eu

O(1);配合物(3)、(4)、(6)、(7)中

、La

、Zn

、Cd

无未充满的d层或f层电子

对Eu

的荧光有增强作用;配合物(5)中的Gd

有4f

半充满稳定电子层结构

对Eu

的荧光也有增强作用。在配合物(8)和(9)中

和Ni

的未充满d层电子消耗配体吸收的能量

对Eu

的荧光有猝灭作用。

Abstract

Nine doped europium benzene-1

5-tricarboxylate complexes have been synthesized and characterized. Elemental analysis

rare earth coordination titration

IR spectra

UV absorption spectra and TG-DTA were used to characterized these complexes. The studies of the fluorescence spectra and lifetimes of the nine complexes show obviously difference. Compared with binary complex of Eu

O(1)

the ternary complex Eu

1.5

O exhibits stronger luminescence intensity. This result indicates that the fluorescence intensities of the complexes depend on ligands. In the binary complex the ligand (btc) transfers some energy to Eu

but in ternary complexes both the ligands (btc and phen) transfer more energy. The fluorescence peak positions of the other seven are similar to (1) and (2)

but the luminescence intensities of these complexes are obviously different. The positions of Eu

emission peak of the complexes do not change

indicating that the introduction of doped rare earth ions or transition-metal ions does not influence the energy level of Eu

in the complexes. The dinuclear complexes

which contain the metal ions Y

and Cd

without unsa-turated d-layer or f-layer electrons

display sensitization and strengthening to fluorescence properties of those complexes

respectively. Therefore

the energy absorption by organic ligands will not be consumed by the d-d or f-f transfer. In this manner

absorbs much more energy through intramolecular energy transfer and luminous intensity is enhanced. Gd

has inert half-full 4f

electronic configuration

so the luminous intensity of (5) is also strong and similar with (3) and (4). Complexes (8) and (9)

containing Mn

and Ni

respectively

exhibit fluorescence quenching

which is caused by the unsaturated d-layer electrons consuming the energy in the form of radiative transition.

关键词

Keywords

references

De Silva C R, Wang R Y, Zheng Z P. Highly luminescent Eu(Ⅲ) complexes with 2,4,6-tri(2-pyridyl)-1,3,5-triazine ligand: Synthesis, structural characterization, and photoluminescence studies [J]. Polyhedron, 2006, 25 (17):3449-3455.[2] Sabbatini N, Guardigli N, Lehn J M. Luminescent lanthanide complexes as photochemical supramolecular devices [J]. Coord. Chem. Rev., 1993, 123 (1-2):201-228.[3] Khreis O M, Curry R J, Somertom M, et al. Infrared organic light emitting devices using neodymium tris-(8-hydro oxyquoline) [J]. J. Appl. Phys., 2000, 88 (1):777-780.[4] Yang Hong, Cai Lihua. Studies on the spectra of rare earth dinuclear complexes with o-phenanthroline hydrate [J]. Chin. J. Spectroscopy Laboratory (光谱实验室), 2003, 20 (1):18-20 (in Chinese).[5] Zhang Renjie, Yang Kongzhang. Fluorescence character of rare earth complex with high efficient green light in ordered molecular films [J]. Longmuir, 1997, 13 (26):7141-7145.[6] Ishizaka T, Tero-Kubota S, Kurokawa Y. EPR studies on defects in sol-gel derived alumina films [J]. J. Phys. Chem. Solids, 2003, 64 (5):801-806.[7] Wu Renqimuge, Zhao Yongliang, Wei Xiaoyan, et al. Synthesis, characterization and fluorescence properties of the solid complexes of rare earth with trimesic acid and 1,10-phenanthroline [J]. China Rare Earths (稀土), 2009, 30 (2):1-4 (in Chinese).[8] Zhang Mei, Zhao Yongliang, Zhao Yanfang, et al. Studies on fluorescence property of Eu3+ dinuclear complexes with 2-thiopheneacetic acid and o-phenanthroline [J]. Chin. J. Lumin. (发光学报), 2008, 29 (5):827-832 (in Chinese).[9] Manhass B S, Trikha A K. The relationship between the direction of shifts in carbon-oxygen stretching frequencies of carboxylate complexes and the type of carboxylate coordination [J]. J. India. Chem. Soc., 1982, 6 :315-319.[10] Zhao Yongliang, Zhao Fengying. Study on infrared and fluorescence spectra of Eu(La) complexes with o-phenanthroline and p-phthalic acid [J]. J. Chin. Rare Earth Society (中国稀土学报), 2001, 19 (5):398-401 (in Chinese).[11] Wang Liufang, Wu Jigui, Peng Zhouren, et al. Study on ternary complexes of rare earth elements Ⅳ. Syntheses and properties of ternary complexes of rare earth elements with 3,5-dinitrosalicylic acid and phenanthroline [J]. Chinese Journal of Inorganic Chemistry (无机化学学报), 1990, 48 (2):141-146 (in Chinese).[12] Wei Xiaoyan, Zhao Yongliang, Xue Zhen, et al. Synthesis, characterization and fluorescence property of Dy3+ with halobenzoic acid and nitrogen-heterocyclic complexes [J]. Chin. J. Lumin. (发光学报), 2009, 30 (1):108-112 (in Chinese).[13] Zhao Yongliang, Zhao Fengying, Xue Zhen, et al. Infrared spectra and luminescent properties of p-tert-butylcalic[8] arene-DMF complexes of rare earth nitrates [J]. Chin. J. Lumin. (发光学报), 2006, 27 (3):358-362 (in Chinese).

Views

143

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Synthesis, Characterization and Fluorescence Properties of Y³⁺ -Doped Terbium Complexes with Phenoxyacetic Acid and 1,10-Phenanthroline

Synthesis, Characterization and Fluorescence Property of Dy<sup>3+</sup> with Halobenzoic Acid and Nitrogen-heterocyclic Complexes

Analysis of Fluorescence Characteristic in High-energy Pulsed Fiber Laser

作用光谱模拟法小白菜高产栽培研究

Related Author

DU Yan

MA Rui-jun

WEI Xiao-yan

LI Huan-huan

ZHAO Yong-liang

WANG Yan

薛珍

于彦珠

Related Institution

College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot

State Key Laboratery of Rare Earth Materials Chemistry and Applications, Peking University

College of Science, Inner Mongolia Agriculture University, Huhhot 010019, China

School of Optoelectronic Information, University of Electronic Science and Technology of China

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰