Properties of Er3+/Yb3+ Co-doped Phosphate Glass-ceramics

WANG Rui; HAN Pei-ze; YU Xiao-chen; WANG Lei; LUO Lan-jun; SONG Feng

doi:null

您当前的位置：

首页 >

文章列表页 >

Properties of Er³⁺/Yb³⁺ Co-doped Phosphate Glass-ceramics

paper | 更新时间：2020-08-12

- Properties of Er³⁺/Yb³⁺ Co-doped Phosphate Glass-ceramics
- Chinese Journal of Luminescence Vol. 31, Issue 6, Pages: 800-805(2010)
- 作者机构：
  
  南开大学物理学院光子学中心天津,300071
- 作者简介：
- 基金信息：
- DOI：
  CLC： O482.31
- Received：13 October 2009，
  
  Revised：18 December 2009，
  
  Published Online：22 November 2010，
  
  Published：22 November 2010
- 稿件说明：
移动端阅览
王睿, 韩霈泽, 于晓晨, 王垒, 骆兰军, 宋峰. Er3+/Yb3+共掺杂磷酸盐微晶玻璃的光谱性质[J]. 发光学报, 2010,31(6): 800-805

WANG Rui, HAN Pei-ze, YU Xiao-chen, WANG Lei, LUO Lan-jun, SONG Feng. Properties of Er3+/Yb3+ Co-doped Phosphate Glass-ceramics[J]. Chinese Journal of Luminescence, 2010,31(6): 800-805
王睿, 韩霈泽, 于晓晨, 王垒, 骆兰军, 宋峰. Er3+/Yb3+共掺杂磷酸盐微晶玻璃的光谱性质[J]. 发光学报, 2010,31(6): 800-805 DOI：

WANG Rui, HAN Pei-ze, YU Xiao-chen, WANG Lei, LUO Lan-jun, SONG Feng. Properties of Er3+/Yb3+ Co-doped Phosphate Glass-ceramics[J]. Chinese Journal of Luminescence, 2010,31(6): 800-805 DOI：

摘要

采用高温熔融法生长了Er

/Yb

共掺杂的磷酸盐微晶玻璃

测量了微晶玻璃室温下的吸收光谱。由此吸收谱

根据Judd-Ofelt理论

计算了Er

/Yb

共掺杂磷酸盐微晶玻璃的强度参数、自发辐射几率、荧光分支比等光谱参数

得到了吸收截面曲线

并根据McCumber理论得到1540nm附近的积分发射截面。样品的强度参数为

=6.3310

-20

=1.4110

-20

=1.0910

-20

。1540nm对应的积分发射截面峰值为1.810

-20

。另外

还测量了Er

/Yb

共掺杂磷酸盐微晶玻璃在980nm激发下的上转换光谱

讨论了Er

/Yb

共掺杂磷酸盐微晶玻璃的上转换发光和能量传递过程。

Abstract

/Yb

co-doped phosphate glass-ceramics have been fabricated and characterized

the formation of Er(PO

)

and Yb(PO

)

nanocrystals were studied using X-ray diffraction. The intensity parameters

the spontaneous radiative transition probabilities

the branching ratios

and the radiative lifetimes of Er

in glass ceramics were calculated based on the Judd-Ofelt theory.For Er

13/2

15/2

transition

lifetime is 8.625 8 ms.Strength parameters are

=6.3310

-20

=1.4110

-20

=1.0910

-20

.According to McCumber theory

we calculated the stimulated emission cross section

the number is 3.610

-21

.We also studied the fluorescence properties of crystals

and the crystal has been pumped up in laser under the green fluorescence conversion.

关键词

Keywords

references

Yu X C, Song F, Wang W T, et al. Comparison of optical parameters and luminescence between Er3+ /Yb3+ codoped phosphate glass ceramics and precursor glasses [J]. J. Appl. Phys., 2008, 104 (11):113105-1-4.[2] Meng J, Zhao L J, Yu H, et al. Luminescent properties in Er-Yb-doped oxyfluoride glass ceramics with a nanocrystal line structure [J]. Acta Phys. Sin.(物理学报), 2005, 54 (3):1442-1446 (in Chinese).[3] Qiao X S, Fan X P, Wang M Q, et al. Spectroscopy properties of Er3+ /Yb3+ co-doped 50SiO2-20Al2O3-30CaF2 glass and glass ceramics [J]. J. Phys.: Condens Matter, 2006, 18 (29):6937-6951.[4] Zheng Z Q, Li X Y, Liu J, et al. Optical properties of Er3+/Yb3+ co-doped transparent PLZT ceramic [J]. Physica B:Condens Matter, 2008, 403 (1):44-49.[5] Liu Z P, Hu L L, Dai S X, et al. Laser properties of Er3+,Yb3+ co-doped erbium phosphate glass pumped by laser diode[J]. Chin. J. Lumin.(发光学报), 2002, 23 (3):238-242 (in Chinese).[6] Zou K S, Lu M, Xiang L B, et al. Yb3+-doped fluoride lead silicate glasses [J]. Acta Photon. Sin.(光子学报), 2008, 37 (12):2504-2507 (in Chinese).[7] Liu Z P, Hu L L, Zhang D B, et al. Judd-Ofelt parameter analysis and spectroscopic properties of Er3+-doped phosphate glasses [J]. Acta Phys. Sin. (物理学报), 2002, 51 (11):2629-2634 (in Chinese).[8] Zou X L, Izumitani T. Spectroscopic properties and mechanisms of excited state absorption and energy transfer upconversion for Er3+-doped glasses [J]. J. Non-Cryst.Solids, 1993, 162 (1-2):68-80.[9] Zhou G, Dai S X, Yu C L, et al. Spectroscopic properties of Er3+,Yb3+ co-doped tellurite glass ceramics containing nanocrystals [J]. J. Chin. Rare Society (中国稀土学报), 2005, 23 (5):518-523 (in Chinese).[10] Li T, Zhang Q Y, Feng Z M, et al. Spectroscopic properties of Er3+-doped alkaline/alkaline-earth metal modified fluorophosphate glasses [J]. Acta Phys. Sin. (物理学报), 2005, 54 (10):4926-4937 (in Chinese).[11] Peng Y, Li S F, Zhang Q Y, et al. Photoluminescence and its physical mechanism of Er/Yb co-doped borate-silicate glass [J]. Acta Phys. Sin. (物理学报), 2007, 56 (12):7286-7294 (in Chinese).

Views

157

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Effect of Doping Rare-earth Concentrations on The Luminescence Spectrum of NaYF₄：Yb³⁺,Tm³⁺ Nanocrystals

The Upconversion Luminescence Properties of Nanocrystal NaYF4 : Er3+,Tm3+, Yb3+ Synthesized by Hydrothermal Method

Up-conversion Luminescence Properties of Yb³⁺/Tm³⁺ Co-doped Silicate Glasses

Upconversion Luminescence of ZBLAN：Yb³⁺, Tm³⁺ Co-excited by Double-frequency with Both 808 and 980 nm Lasers

Laser Properties of Er³⁺,Yb³⁺ Co-doped Erbium Phosphate Glass Pumped by Laser Diode

Related Author

LI Xiao-kun

SONG Shu-guang

KONG Xiang-gui

ZHAO Cheng-zhou

张月平

杨魁胜

翟海青

李岳

Related Institution

State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

University of Chinese Academy of Sciences

School of Material Science and Engineering, Changchun University of Science and Technology

Applied Chemistry Department, College of Chemistry, Northeast Normal University

Key Laboratory of Special Glass in Hainan Province, Hainan University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰