Investigation of The Characteristics of Oleic Modified LaF3:Er,Yb Nanoparticle and Fabrication of Inorganic-organic Hybrid Waveguide Amplifier

LIU Tian-ji; LI Tong; CHEN Cong; CHEN Chang-ming; ZHANG Da-ming

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Investigation of The Characteristics of Oleic Modified LaF₃:Er,Yb Nanoparticle and Fabrication of Inorganic-organic Hybrid Waveguide Amplifier

paper | 更新时间：2020-08-12

- Investigation of The Characteristics of Oleic Modified LaF₃:Er,Yb Nanoparticle and Fabrication of Inorganic-organic Hybrid Waveguide Amplifier
- Chinese Journal of Luminescence Vol. 31, Issue 6, Pages: 899-903(2010)
- 作者机构：
  
  吉林大学电子科学与工程学院集成光电子学国家重点联合实验室,吉林长春,130012
- 作者简介：
- 基金信息：
- DOI：
  CLC： TN256
- Received：12 February 2010，
  
  Revised：06 May 2010，
  
  Published Online：22 November 2010，
  
  Published：22 November 2010
- 稿件说明：
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刘天际, 李彤, 陈聪, 陈长鸣, 张大明. 油酸修饰的LaF3:Er,Yb纳米颗粒的光学特性及有机-无机复合型光波导放大器[J]. 发光学报, 2010,31(6): 899-903

LIU Tian-ji, LI Tong, CHEN Cong, CHEN Chang-ming, ZHANG Da-ming. Investigation of The Characteristics of Oleic Modified LaF3:Er,Yb Nanoparticle and Fabrication of Inorganic-organic Hybrid Waveguide Amplifier[J]. Chinese Journal of Luminescence, 2010,31(6): 899-903
刘天际, 李彤, 陈聪, 陈长鸣, 张大明. 油酸修饰的LaF3:Er,Yb纳米颗粒的光学特性及有机-无机复合型光波导放大器[J]. 发光学报, 2010,31(6): 899-903 DOI：

LIU Tian-ji, LI Tong, CHEN Cong, CHEN Chang-ming, ZHANG Da-ming. Investigation of The Characteristics of Oleic Modified LaF3:Er,Yb Nanoparticle and Fabrication of Inorganic-organic Hybrid Waveguide Amplifier[J]. Chinese Journal of Luminescence, 2010,31(6): 899-903 DOI：

摘要

采用微乳液法制备了LaF

:Er

Yb纳米颗粒

在有机-无机杂化材料中有良好的溶解性

掺杂质量比可达到50%。通过TEM观察到纳米颗粒的粒径为6~10nm;XRD的测试结果表明材料中形成了LaF

六方晶体结构;荧光发射谱的测试表明纳米颗粒的荧光半峰全宽为79nm;通过时间相关单光子计数法测得铒离子

13/2

能级的寿命为100s。结合半导体工艺

制备了嵌入条形结构的平面光波导放大器

在信号光(1550nm)功率为0.2mW

泵浦光(980nm)功率为188mW的条件下

在1.9cm的样品上得到了3.2dB的相对增益;同时分析了散射损耗随颗粒大小的变化关系。

Abstract

In this paper

oleic modified LaF

:Er

Yb nanoparticle (NP) is prepared by micro-emulsion method. This NP has a excellent solubility in organic solvent and NPs doping concentration can reach as high as 50%. Observed by TEMs photograph

most of NPs diameter is about 6~10 nm; there is hexagonal LaF

structure in the materials by X-ray diffraction pattern; NP shows potential high gain bandwidth because full width at half maximum (FWHM) is 79 nm which is bigger than inorganic matrix erbium doped waveguide amplifier (EDWA); 100 s lifetime of the

13/2

energy level is also measured. At last

a planar waveguide is fabricated by semiconductor process

a relative gain of 3.2 dB can be got in a 1.9 cm length sample with 1 mW signal power. The relationship between gain and nanopaticle diameter is also analyzed.

关键词

Keywords

references

Zhang Xizhen. Fundamental research on polymer optical waveguide amplifier in the 1.55 m wavelength region . Changchun: Jilin University, 2007.[2] Zhang Dan. An experimental and theoretical study on erbium-doped polymer waveguide amplifier . Changchun: Jilin University, 2008.[3] Anh Quoc Le Quang, Rolland Hierle, Joseph Zyss, et al. Demonstration of net gain at 1 550 nm in an erbium-doped polymer single mode rib waveguide [J]. Appl. Phys. Lett., 2006, 89 (14):141124-1-3.[4] Wong W H, Chan K S, Pun E Y B, et al. Ultraviolet direct printing of rare-earth-doped polymer waveguide amplifiers [J]. Appl. Phys. Lett., 2005, 87 (1):011103-1-3.[5] Wang Jianshe, Hu Jin, Tang Daihua, et al. Oleic acid (OA)-modified LaF3 ∶ Er,Yb nanocrystals and their polymer hybrid materials for potential optical-amplification applications [J]. J. Mater. Chem., 2007, 17 (16):1597-1601.[6] Jan W Stouwdam, Gerald A Hebbink, Jurriaan Huskens, et al. Lanthanide-doped nanoparticles with excellent luminescent properties in organic media [J]. Chem. Mater., 2003, 15 (24):4604-4616.[7] Bok Yeop Ahn, Sang Il Seok, Suk-In Hong, et al. Optical properties of organic/inorganic nanocomposite sol-gel films containing LaPO4 ∶ Er,Yb nanocrystals [J]. Optical Materials, 2006, 28 (4):374-379.[8] Zhang Jishuang, Qin Weiping, Zhang Jisen, et al. Bright blue upconversion emission of LaF3 ∶ Yb3+ , Tm3+ nanoparticles [J]. Chin. J. Lumin. (发光学报), 2008, 29 (4):660-664 (in Chinese).[9] Song Hongwei. Recent developments on rare earth doped oxide nanocrystals [J]. Chin. J. Lumin. (发光学报), 2008, 29 (6):921-936 (in Chinese).[10] Wong S F, Pun E Y B, Chun P S, et al. Er3+/Yb3+ codoped phosphate glass waveguide amplifier using Ag+-Li+ ion exchange [J]. IEEE Photon. Tech. Lett., 2002, 14 (1):80-82.[11] Liu K, Pun E Y B. K+-Na+ ion-exchanged waveguides in Er3+-Yb3+ codoped glasses using field-assisted annealing [J].Appl. Opt., 2004, 43 (15):3179-3184.[12] Dekker R, Klunder D J W, Borreman A, et al. Stimulated emission and optical gain in LaF3 ∶ Nd nanoparticle-doped polymer-based waveguides [J]. Appl. Phys. Lett., 2004, 85 (25):6104-6106.[13] Stouwdam Jan W, Frank C J M, Van Veggel. Near-infrared emission of redispersible Er3+ , Nd3+, and Ho3+ doped LaF3 nanoparticles [J]. Nano Lett., 2002, 2 (7):733-737.[14] Kumar G A, Chen C W, Ballato J, et al. Optical characterization of infrared emitting rare-earth-doped fluoride nanocrystals and their transparent nanocomposites [J]. Chem. Mater., 2007, 19 (6):1523-1528.

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