and optical properties of the ZnO films prepared by a vapour-phase technique on different substrates were performed in this study. Scanning electron micro-scopy (SEM) data showed that larger ZnO particles are formed on the Au-covered Si substrates than those on Si substrates. X-ray diffraction (XRD) results indicated that hexagonal wurtzite ZnO films are grown on both Si(111) and Si(100) substrates though they present different diffraction peaks with hexagonal wurtzite structure
while appears no sphalerite structure. The ZnO films prepared on Au-coated Si substrates prefer to grow along with
c
-axis orientation. The PL spectra reveal only a narrow strong UV emission peak at about 389 nm (3.19 eV) in all the ZnO samples.
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references
. Huang M H, Mao S, Feick H, et al. Room-temperature ultraviolet nanowire nanolasers [J]. Science, 2001, 292 (5523):1897-1899.
. Morgan J H, Brodie D E. The preparation and some properties of transparent conducting ZnO for use in solar-cells [J]. Can. J. Phys., 1982, 60 (10):1387-1390.
. Vanheusden K, Seager C H, Warren W L, et al. Correlation between photoluminescence and oxygen vacancies in ZnO phosphors [J]. Appl. Phys. Lett., 1996, 68 (3):403-405.
. Li H, Sang J P, Liu C, et al. Microstructural study of MBE-grown ZnO film on GaN/sapphire (0001) substrate [J]. Centr. Eur. J. Phys., 2008, 6 (3):638-642.
. Su Shichen, Lu Youming, Zhang Zhenzhong, et al. Structural and optical properties of high quality MgxZn1-xO films grown by P-MBE [J]. Chin. J. Lumin. (发光学报), 2008, 29 (2):309-312 (in Chinese).
. Li Z Y, Xu F C, Wu Q H, et al. Zinc oxide thin film synthesized by combustion chemical vapor deposition [J]. Appl. Sur. Sci., 2008, 255 (5):2859-2863.
. Tian Ke, Shi Yuanyuan, Xu Xiaoqiu, et al. The investigation of growth orientation of ZnO films by CVD [J]. Chin. J. Lumin. (发光学报), 2008, 29 (2):294-298 (in Chinese).
. Mycielski A, Kowalczyk L, Szadkowski A, et al. The chemical vapour transport growth of ZnO single crystals [J]. J. Alloys Compd, 2004, 371 (1-2):150-152.
. Ntep J M, Hassani S S, Lusson A, et al. ZnO growth by chemical vapour transport [J]. J. Cryst. Growth, 1999, 207 (1-2):30-34.
. Shiloh M, Gutman J. Growth of ZnO single crystals by chemical vapour transport [J]. J. Cryst. Growth, 1971, 11 (2):105-107.
. Li J, Srinivasan S, He G N, et al. Synthesis and luminescence properties of ZnO nanostructures produced by the sol-gel method [J]. J. Cryst. Growth, 2008, 310 (3):599-603.
. Xu F, Lu Y N, Xia L L, et al. Seed layer-free electrodeposition of well-aligned ZnO submicron rod arrays via a simple aqueous electrolyte [J]. Mater. Res. Bull., 2009, 44 (8):1700-1708.
. Janfeshan B, Bahrevar M, Ahmadi K. ZnO nanorods grown by carbothermal evaporation [J]. Internat. J. Modern Phys., B, 2008, 22 (18-19):3289-3295.
. Deng S, Fan H M, Zhang X, et al. An effective surface-enhanced Raman scattering template based on a Ag nancluster-ZnO nanowire array [J]. Nanotech., 2009, 20 (17):175705-1-7.
. Zhang Y, Jia H B, Yu D P, et al. Low-temperature growth and Raman scattering study of vertically aligned ZnO nanowires on Si substrate [J]. Appl. Phys. Lett., 2003, 83 (22):4631-4633.
. Vanheusden K, Warren W L, Seager C H, et al. Mechanisms behind green photoluminescence in ZnO phosphor powders [J]. J. Appl. Phys., 1996, 79 (10):7983-1990.