Synthesis, Characterization and Fluorescence Properties of A Novel Europium Complex Based on 2,2'-bipyridine- 3,3'-dicarboxylate Ligand in Solution

LI Bin; CHEN Qiu-yun; ZHANG Rong-xian; FU Hai-jian; WANG Ling-yun

doi:null

您当前的位置：

首页 >

文章列表页 >

Synthesis, Characterization and Fluorescence Properties of A Novel Europium Complex Based on 2,2'-bipyridine- 3,3'-dicarboxylate Ligand in Solution

paper | 更新时间：2020-08-12

- Synthesis, Characterization and Fluorescence Properties of A Novel Europium Complex Based on 2,2'-bipyridine- 3,3'-dicarboxylate Ligand in Solution
- Chinese Journal of Luminescence Vol. 30, Issue 6, Pages: 847-851(2009)
- 作者机构：
  
  江苏大学化学化工学院,江苏镇江,212013
- 作者简介：
- 基金信息：
- DOI：
  CLC： O482.31;O614.33
- Received：14 March 2009，
  
  Revised：02 January 1900，
  
  Published Online：30 December 2009，
  
  Published：30 December 2009
- 稿件说明：
移动端阅览
LI Bin, CHEN Qiu-yun, ZHANG Rong-xian, et al. Synthesis, Characterization and Fluorescence Properties of A Novel Europium Complex Based on 2,2'-bipyridine- 3,3'-dicarboxylate Ligand in Solution[J]. Chinese journal of luminescence, 2009, 30(6): 847-851.
DOI：

LI Bin, CHEN Qiu-yun, ZHANG Rong-xian, et al. Synthesis, Characterization and Fluorescence Properties of A Novel Europium Complex Based on 2,2'-bipyridine- 3,3'-dicarboxylate Ligand in Solution[J]. Chinese journal of luminescence, 2009, 30(6): 847-851. DOI：

摘要

合成了一种新的以TTA(а-噻吩甲酰三氟丙酮)、H

bpdc(2

2'-联吡啶-3

3'-二羧酸)为配体

单一稀土Eu

的三元配合物。通过元素分析、差热分析、红外光谱、紫外光谱、发光光谱对其进行了表征。发现在中性和弱碱性条件下配合物在醇-水溶液中的发射光谱表现出较强的Eu

离子的特征发射

且Eu

离子的发光强度随pH值改变发生变化

可作为生物医学和食品检测用pH敏感的荧光探针。

Abstract

A novel europium(Ⅲ) complex was synthesized using TTA (α-thenoyltrifluoroacetone) as the first ligand and H

bpdc (2

2'-bipyridine-3

3'-dicarboxylate) as the second ligand. Elemental analysis

thermal analysis

IR and UV-Vis spectrum analysis and fluorescence spectra of the europium(Ⅲ) complex were carried out. Fluorescence properties of the complex in ethanol-aqueous solution were studied

which indicated that the europium(Ⅲ) complex exhibits a strongly characteristic red luminescence of Eu

. The Eu

emission is very sensitive to pH value

so the complex can be used as pH-dependent fluorescence probe in biomedicine and food detection.

关键词

Keywords

references

. Kido J, Nagai K, Okamoto Y, et al. Electroluminescence from polysilane film doped with europium complex [J]. Chem. Lett., 1991, 20 :1267-1270.

. Li Wenxian, Zhang Ruiping, Guo Lei, et al. Synthesis of phenylacetic and rare earth complexes at low temperature solid state reaction and luminescence property of Eu3+,Tb3+ complexes [J]. Chin. J. Lumin. (发光学报), 2007, 28 (2):207-213 (in Chinese).

. Xu Lijuan, Wang Ruifen, Zhao Na, et al. Synthesis and properties of ternary terbium complexes with halogen-benzoic acid and 10-phenanthroline [J]. Chin. J. Lumin. (发光学报), 2007, 28 (5):281-287 (in Chinese).

. Qiu Fengxian, Xu Hongliang, Da Zulin, et al. Synthesis, characterization and fluorescence property of rare earth neodynium with oxalic acid and acrylic acid [J]. Chin. J. Lumin. (发光学报), 2007, 28 (6):930-934 (in Chinese).

. Wang Lianmeng, Zhao Yongliang, Zhou Yongsheng, et al. Synthesis,characterization and photoluminescence properties of Eu<em>xRE1-x (FTFA)3phen complexes [J]. Chin. J. Lumin. (发光学报), 2008, 29 (6):1086-1090 (in Chinese).

. McGehee M D, Bergstedt T, Zhang C, et al. Narrow bandwidth luminescence from blends with energy transfer from semiconducting conjugated polymers to europium complexes [J]. Adv. Mater., 1999, 11 (16):1349-1354.

. Shi Xiaoyan, Li Wenxian, Qin Caihua, et al. Synthesis and characterization of quaternary complexes of light rare earth perchlorate with diphenyl sulfoxide, benzoic acid and studies on fluorescence of Eu3+ complex [J]. Chin. J. Lumin. (发光学报), 2008, 29 (5):772-778 (in English).

. Sun Peipei, Duan Jiunpey, Cheng Chienhong, et al. Synthesis of new europium complex and their application in electroluminescent devices [J]. Adv. Funct. Mater., 2003, 13 (9):683-691.

. Chen Fangfang, Guan Min, Huang Chunhui, et al. Synthesis, photoluminescence and electroluminescence properties of a new binuclear Eu(Ⅲ) complex [J]. Acta Chim. Sinica (化学学报), 2005, 63 (7):663-666 (in Chinese).

. Silva C R D, Li Fuyou, Huang Chunhui, et al. Europium β-diketonates for red-emitting electroluminescent devices [J]. Thin Solid Films, 2008, 517 (2):957-962.

. Guo Hongyou, Chen Chunxue, Wei Yongge, et al. A novel coordination polymer, n(bpdc=2,2'-bipyridyl-3,3'-dicarboxylate): coordination models of bpdc ligands [J]. Chin. J. Chem., 2004, 22 (8):816-821.

. Guo Guangsheng, Liu Yangchun, Zhang Jia, et al. A series of rare earth coordination polymer constructed from paddle-wheel building blocks [J]. J. Rare Earths, 2008, 26 (5):633-637.

. Chen Zhimin, Li Dongping, Li Huiquan, et al. Synthesis, crystal structure of a novel 2D network manganese(Ⅱ) polymer bridged by 2,2-bipyridine-3,3-dicarboxylate [J]. Chin. J. Inorg. Chem. (无机化学学报), 2008, 24 (11):1907-1911.

. Hu Ming, Wang Qinglun, Xu Gongfeng, et al. First examples of ternary lanthanide 2,2'-bipyridine-3,3'-dicarboxylate coordination polymers with zigzag chains structures assembled from lanthanide ions, 2,2'-bipyridine-3,3'-dicarboxylate and 1,10-phenanthroline [J]. Inorg. Chim. Acta, 2007, 360 (5):1684-1690.

. Ma Ruixia, Wang Ruifen, Wang Shuping, et al. Synthesis and properties of ternary europium complexes with aromatic carboxylic acid and nitrogen-containing heterocyclic ligand [J]. J. Chin. Rare Earth Soc. (中国稀土学报), 2006, 24 (3): 274-278 (in Chinese).

. Zhang Mei, Zhao Yongliang, Zhao Yanfang, et al. Studies on fluorescence property of Eu3+ dinuclear complexes with 2-thiopheneacetic acid and o-phenanthroline [J]. Chin. J. Lumin. (发光学报), 2008, 29 (5):827-832 (in Chinese).

. Hugo G, Gilmar G, Patricia T, et al. Synthesis, crystal structure and luminescent properties of new tris-β-diketonate Eu(Ⅲ) complex with thiadiazolophenanthroline derivative ligand [J]. Inorg. Chem. Commun., 2008, 11 (10):1292-1296.

. Pan Yuanfeng, Xiao Huining, He Beihai, et al. Synthesis and photoluminescence properties of europium-doped complexes [J]. Chin. Rare Earths (稀土), 2008, 29 (6):26-30 (in Chinese).

. Chen Dongqing, Guo Dongcai, Xia Liangshu. Interaction of fluorescence property of complexes of rare earth (Eu-Tb) [J]. Chin. J. Appl. Chem. (应用化学), 2007, 24 (10):1157-1161 (in Chinese).

. Chen Jian, Xu Huixia, Du Hong, et al. Synthesis and photoluminescent property of a novel europium(Ⅲ) complex [J]. J. Chin. Rare Earth Soc. (中国稀土学报), 2008, 26 (2):239-243 (in Chinese).

Views

447

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Synthesis and Luminescence of Dinuclear Eu(Ⅲ) Complex Based on 4,4'-bis -m-diphenylbene

Synthesis,Characterization and Photoluminescence Properties of (EuxRE_1-x)(FTFA)₃Phen Complexes

Studies on Fluorescence Property of Eu³⁺ Dinuclear Complexes with₂-Thiopheneacetic Acid and o-Phenanthroline

Preparation and Properties of SiO₂ Coating Europium (Ⅲ) Complex Fluorescent Nanoparticles

Fluorescence Property of Eu³⁺,Tb³⁺Terephthalic Acid and 18-Crown-6 Complexes Doped by Non-fluorescence Rare Earth

Related Author

GUO Jin-yuan

PAN Rong-kai

TANG Si-ping

LIU Sheng-gui

WEI Xiao-yan

ZHOU Yong-sheng

ZHAO Yong-liang

WANG Lian-meng

Related Institution

State Key Laboratory of Rare Earth Materials and Applications, Peking University

College of Chemistry and Chemical Engineering, Inner Mongolia University

The College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot

Department of Chemistry, Xiaogan College

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰