The Design and Characterization of Inorganic/Organic Hybrid Luminescence Molecule Materials with Terbium-sulfosalicylic Acid Complexes

ZHAO Li-min; SHAO Xin; KONG Ying

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The Design and Characterization of Inorganic/Organic Hybrid Luminescence Molecule Materials with Terbium-sulfosalicylic Acid Complexes

paper | 更新时间：2020-08-12

- The Design and Characterization of Inorganic/Organic Hybrid Luminescence Molecule Materials with Terbium-sulfosalicylic Acid Complexes
- Chinese Journal of Luminescence Vol. 30, Issue 6, Pages: 862-866(2009)
- 作者机构：
  
  聊城大学材料科学与工程学院,山东聊城,252059
- 作者简介：
- 基金信息：
- DOI：
  CLC： O482.31
- Received：20 January 2009，
  
  Revised：02 January 1900，
  
  Published Online：30 December 2009，
  
  Published：30 December 2009
- 稿件说明：
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ZHAO Li-min, SHAO Xin, KONG Ying. The Design and Characterization of Inorganic/Organic Hybrid Luminescence Molecule Materials with Terbium-sulfosalicylic Acid Complexes[J]. Chinese journal of luminescence, 2009, 30(6): 862-866.
DOI：

ZHAO Li-min, SHAO Xin, KONG Ying. The Design and Characterization of Inorganic/Organic Hybrid Luminescence Molecule Materials with Terbium-sulfosalicylic Acid Complexes[J]. Chinese journal of luminescence, 2009, 30(6): 862-866. DOI：

摘要

通过对5-磺基水杨酸进行化学修饰并引入偶联基团

同Tb

配位后与正硅酸乙酯水解缩聚来制备以强化学键结合的光功能杂化材料。利用紫外光谱、核磁共振等来表征中间体和材料的结构。荧光数据表明:材料表现出Tb

的特征光谱

并具有良好的发光性能。

Abstract

5-sulfosalicylic acid was modified by the amidation reaction by a crosslinking molecule (3-amino- propyl)trimethoxysilane. The modified functional ligand further behaves as a bridge both coordinates to terbium ion and occurs by in-situ sol-gel process with tetraethoxysilane

resulting in a novel hybrid material. Ultraviolet absorption and nuclear magnetic resonance were applied to characterize the obtained hybrid mate-rial. Fluorescence spectra showed the strong luminescence of terbium ion in the complex.

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Keywords

references

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