Preparation,Morphology and Luminescent Property of Poly(vinylidene difluoride)/(Y0.97Eu0.03)2O3 Rare-earth Nanocomposite

XU Chun-hua; OUYANG Chun-fa; JIA Run-ping; WANG Xia

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Preparation,Morphology and Luminescent Property of Poly(vinylidene difluoride)/(Y_0.97Eu_0.03)₂O₃ Rare-earth Nanocomposite

更新时间：2020-08-12

- Preparation,Morphology and Luminescent Property of Poly(vinylidene difluoride)/(Y_0.97Eu_0.03)₂O₃ Rare-earth Nanocomposite
- Chinese Journal of Luminescence Vol. 29, Issue 5, Pages: 779-783(2008)
- 作者机构：
  
  上海应用技术学院, 材料工程系上海,200235
- 作者简介：
- 基金信息：
  
  The Project supported by the Key Subject Construction Projectin Shanghai (p1502);t
- DOI：
  CLC： O482.31
- Received：20 February 2008，
  
  Revised：2008-3-25，
  
  Published：20 September 2008
- 稿件说明：
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许春华, 欧阳春发, 贾润萍, 王霞. 聚偏二氟乙烯/(Y0.97Eu0.03)2O3稀土氧化物纳米复合材料制备、形貌及发光性能[J]. 发光学报, 2008,29(5): 779-783

XU Chun-hua, OUYANG Chun-fa, JIA Run-ping, WANG Xia. Preparation,Morphology and Luminescent Property of Poly(vinylidene difluoride)/(Y0.97Eu0.03)2O3 Rare-earth Nanocomposite[J]. Chinese Journal of Luminescence, 2008,29(5): 779-783
许春华, 欧阳春发, 贾润萍, 王霞. 聚偏二氟乙烯/(Y0.97Eu0.03)2O3稀土氧化物纳米复合材料制备、形貌及发光性能[J]. 发光学报, 2008,29(5): 779-783 DOI：

XU Chun-hua, OUYANG Chun-fa, JIA Run-ping, WANG Xia. Preparation,Morphology and Luminescent Property of Poly(vinylidene difluoride)/(Y0.97Eu0.03)2O3 Rare-earth Nanocomposite[J]. Chinese Journal of Luminescence, 2008,29(5): 779-783 DOI：

摘要

借助超声技术采用一种简便易行的共沉淀方法制备出聚偏二氟乙烯(PVDF)/钇铕稀土氧化物((Y

0.97

0.03

)

)纳米粒子发光纳米复合材料.复合材料的断面形貌和(Y

0.97

0.03

)

纳米粒子在PVDF基体中的分散状态通过扫描电子显微镜(SEM)进行了研究

其发光性质通过荧光光谱进行表征.SEM结果表明:当(Y

0.97

0.03

)

纳米粒子添加量在1%～%时

0.97

0.03

)

纳米粒子在PVDF基体中形成尺寸在0nm～2μm的团聚体

其尺寸随(Y

0.97

0.03

)

添加量增加而增大;当(Y

0.97

0.03

)

添加量小于1%时

0.97

0.03

)

纳米粒子在PVDF基体中实现了较好分散.发光光谱结果表明制备的纳米复合材料具有明显的红光发射特征

对应于(Y

0.97

0.03

)

纳米粒子的本征发射.制备的高分子发光纳米复合材料将来有望在光学材料中获得应用.

Abstract

In this communication

the poly(vinylidene difluoride) (PVDF)/(Y

0.97

0.03

)

rare-earth nanocompositeswere prepared by a facile co-precipitation method with the aid of ultrasonic technique.The cross sections of the nanocomposite were observed by scanning electron microscopy (SEM)

and the luminescent properties of the nanocompositeswere studied by fluorescence spectroscopy.The SEM results showed that the (Y

0.97

0.03

)

nanoparticles were dispersed in PVDF matrix as some aggregateswith the sizes between 50 nm~2μm when themass fraction of (Y

0.97

0.03

)

was between 1% and 5%;while the (Y

0.97

0.03

)

particles were better dispersed in the matrix when the (Y

0.97

0.03

)

mass fraction was lower than 1%.The lumine scence spectra showed a characteristic red-emitting of PVDF/(Y

0.97

0.03

)

nanocomposites at 612 nm

corresponding to the intrinsic luminescence of the Eu

ion in (Y

0.97

0.03

)

nanoparticles.The prepared rare-earth nanocomposites with unique optical characteristicmay be used as opticalmaterials in the future.

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