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中国科学院长春光学精密机械与物理研究所, 应用光学国家重点实验室光学技术中心,吉林 长春,130022
Received:19 July 2002,
Revised:10 September 2002,
Published:20 November 2002
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贾克辉, 徐颖, 高劲松, 曹健林. 等离子辅助镀膜技术[J]. 发光学报, 2002,23(6): 623-626
JIA Ke-hui, XU Ying, GAO Jin-song, CAO Jian-lin. Plasma Ion Assisted Deposition for Optical Coating[J]. Chinese Journal of Luminescence, 2002,23(6): 623-626
传统的电子束蒸发工艺提供了高速率的沉积
但由于成膜分子的能量较低
使沉积的薄膜排列密度很低
其性能和块状材料区别很大
已有不少学者发现了很多金属和氧化物薄膜具有典型的柱状结构。薄膜的低排列密度造成了其光学常数和机械性能不如块状材料
近几年发展起来的高功率等离子体辅助镀膜技术解决了上述问题。本文报道了我国自己研制的等离子体源(GIS)的性能指标、用这个源所做的单层TiO2膜的成膜工艺与质量
以及用等离子辅助沉积的减反射膜的工艺。
Evaporation
the classical method of thin film deposition
is still commonly used for the production of optical coatings today. The technique of electron beam evaporation delivers a high rate of deposition. Three dimensional or curved substrates are also coated by e-beam evaporation in order to achieve good film thickness distribution. Because of the low energy of the condensing particles the packing density of thermally evaporated films is very low. The achieved film properties are quite different to those of the respective bulk materials. The typical columnar microstructure of many metals and oxides has been investigated by various workers. The low packing density implies that the optical constants and mechanical properties are inferior to those of the bulk materials. Deposition processes using higher particle energies can improve the film properties. With ion assisted deposition
a growing thermally evaporated film is bombarded with an energetic ion beam. Due to the momentum transfer from the incoming ions to the condensing molecules
the mobility of the particles is increased significantly. This results in higher packing densities and improved mechanical properties. A wide range of materials and completed layer systems have been investigated by many laboratories. The limited ion current and beam size of the available ion sources reduces the useful substrate area in comparison to conventional evaporation. This is not compatible to the needs of a high throughput production. Most ion sources use hot filament cathodes and extraction grids with limited life time especially when introducing oxygen into the ion source. Many oxides require ionized oxygen during film deposition in order to get fully oxidized films with low absorption losses and high packing densities. With the newly developed high power plasma ion assisted deposition we have overcome these problems. This paper mainly discusses the performance specification of plasma source (GIS)
technology and quality of TiO
2
coatings and the technology for antireflection coatings deposited with plasma-IAD.We can draw a conclusion that the refractive index of TiO
2
film will have different values with the anode current changing and they are 2.25
2.37
2.39
2.42 and 2.43 at wavelength of 520nm respectively. The reflectance of the antireflection coating is lower than 2% in the wavelength range between 450nm and 750nm.
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