HUANG Li-hui, LIU Xing-ren, XU Mai. Optical Transitions of Er<sup>3+</sup> in Cd<sub>3</sub>A1<sub>2</sub>Si<sub>3</sub>O<sub>12</sub> Glass[J]. Chinese Journal of Luminescence, 2001,22(4): 362-366
HUANG Li-hui, LIU Xing-ren, XU Mai. Optical Transitions of Er<sup>3+</sup> in Cd<sub>3</sub>A1<sub>2</sub>Si<sub>3</sub>O<sub>12</sub> Glass[J]. Chinese Journal of Luminescence, 2001,22(4): 362-366DOI:
Er-doped glasses have attracted much research interests due to their application in the area of optical communications
such as fiber amplifiers and lasers
and infrared solid-state lasers.To account for the optical absorption and in turn radiative properties of excited states
the Judd-Ofelt theory has been successfully applied to most of the lanthanide ions.In this paper
the experimental and theoretical oscillator strengths of some levels of Er
3+
ion in Cd
3
Al
2
Si
3
O
12
glass(CAS glass in brief) were calculated using the absorption spectra and Judd-Ofelt theory.The root-mean-square deviation is only 3.30×10
-7
.This result indicates that the theory is in well accord with the experiment results.Based on a least-square fit between experimental and theoretical oscillator strengths
the intensity parameters were determined.The results are Ω
2
=6.42×10
-20
cm
2
;Ω
4
=1.53×10
-20
cm
2
;Ω
6
=0.69×10
-20
cm
2
.Then the radiative transition proba-bility A
radiative lifetime r
branching ratio βand integrated emission cross-sections of radiative transitions of Er
3+
in this glass at room temperature were calculated.According to the large integrated emission cross-emission(1.402×10
-18
cm) and the long lifetime(8.062ms) of the transition of
4
I
13/2
→
4
I
15/2
of Er
3+
in CAS glass
it can be concluded 1.534μm laser oscillation of Er-doped CAS glass is possible to be demon-strated.In addition
this glass has several advantages
such as easy-made
scale-varied
easy-fibered and ad-justable host composition along with their high chemical durability and thermal stability.Therefore
Er-doped CAS glass is a potential near infrared solid-state laser material.
Spectral Parameter Computation of Yb∶GdScO3 Crystal
Luminescence Properties of Tm3+/Ho3+ Doped BaF2 Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm
Luminescence Properties and Judd-Ofelt Analysis of BaGd2ZnO5:Sm3+ Microcrystalline Powders
Spectral Parameter Calculation of Ho3+, Tm3+ Co-doped KYb(WO4)2 Laser Crystal
Up-conversion Luminescent Properties of YNbO4: Tm3+/Yb3+
Related Author
LI Jia-hong
ZHANG Qing-li
SUN Gui-hua
GAO Jin-yun
WANG Xiao-fei
DOU Ren-qin
DING Shou-jun
ZHANG De-ming
Related Institution
School of Science and Engineering of Mathematics and Physics, Anhui University of Technology, Maanshan
University of Science and Technology of China
Advanced Laser Technology Laboratory of Anhui Province
The Key Laboratory of Photonic Devices and Materials, Anhui Province, Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences