XU Chun-xiang, XU Hong-guang, MENG Rui-ping, FENG Xue-yuan, ZHANG Jia-yu, CUI Yi-ping. Electroluminescence of an Organic Pyridyl Salt[J]. Chinese Journal of Luminescence, 2006,27(5): 679-683
XU Chun-xiang, XU Hong-guang, MENG Rui-ping, FENG Xue-yuan, ZHANG Jia-yu, CUI Yi-ping. Electroluminescence of an Organic Pyridyl Salt[J]. Chinese Journal of Luminescence, 2006,27(5): 679-683DOI:
green and blue is the most basic and the most important technology for full color display.Green and blue emission from the organic light emitting diodes (OLED) have been employed successfully to organic display
but the red light performance still need to improved.So far
host-guest system and rare earth complexes were used for red emission.In these two kinds of OLEDs
the energy transfer efficiency were generally limited by the concentration quenching and the phase separation.Ones have paid great effort to explore some novel materials and devices structures for red emission with high perfor-mance.In this paper
an ionic organic pyridyl salt [ASPT (trans-4-[P-(N-ethyl-N-(hydroxylethyl)-amino) styryl]-N-methylpyridinium tetraphenyl-borate) ]
was employed as active layer for an organic light-emitting diode with stable red emission.The investigation on the electroluminescent properties demonstrated that ASPTis a good luminescent molecule for red emission.Astable red electroluminescence was obtained by using this material as emitting layer in a monolayer structure.The luminescence mechanism was discussed based on the influence of the external electrical field on the energy barrier in the interfaces between the active layer and the electrodes.In order to understand the charier charge transport and their recombination process
and to improve the ELperformance
double-layer TPD/ASPTor ASPT/Alq
3
and triple-layer TPD/ASPT/Alq
3
structures were designed and the ELproperties were further studied.Brighter red ELand red-blue variable emission depended on the applied voltage were observed in the double-layer and the triple-layer structures
respectively.Consi-dering the different function of each layer in the triple-layer structure
the color variation is assumed to the change of the recombination region.The mechanism was discussed by analyzing the spectra and the corresponding energy level structures.