Synthesize and Optical Properties of Si-B-C-N Bamboo Nanomaterial from Polymer
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Synthesize and Optical Properties of Si-B-C-N Bamboo Nanomaterial from Polymer
Chinese Journal of LuminescenceVol. 26, Issue 3, Pages: 391-394(2005)
作者机构:
1. 中国科学院, 激发态物理重点实验室,吉林 长春,130033
2. 吉林大学, 物理学院, 吉林, 长春, 130021
作者简介:
基金信息:
DOI:
CLC:O472.3;O482.31
Published:20 May 2005,
Received:22 August 2004,
Revised:21 December 2004,
稿件说明:
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WANG YAN-SONG, XU SHI-FENG, FAN YI, et al. Synthesize and Optical Properties of Si-B-C-N Bamboo Nanomaterial from Polymer. [J]. Chinese journal of luminescence, 2005, 26(3): 391-394.
DOI:
WANG YAN-SONG, XU SHI-FENG, FAN YI, et al. Synthesize and Optical Properties of Si-B-C-N Bamboo Nanomaterial from Polymer. [J]. Chinese journal of luminescence, 2005, 26(3): 391-394.DOI:
Synthesize and Optical Properties of Si-B-C-N Bamboo Nanomaterial from Polymer
Si-B-C-N materials derived from polymer precursors recently received a high attention due to their outstanding high temperature stability. It has been reported that the precursor-derived Si-B-C-N materials do not degrade at temperatures up to 2000℃
even in nitrogen-free environments. In addition
they possess superior mechanical properties such as excellent creep and oxidation resistance. Therefore these materials are promising for components which were serve at temperatures above 1000℃
such as turbine parts.Much studies have focused on amorphous Si-B-C-N materials
while especially studies on crystal Si-B-C-N nano-materials are still under the way.We focus on the optical properties of Si-B-C-N nanomaterials derived from boron-modified polysilazanes precursors. Scanning electronic microscopy (SEM) and high transmission electronic microscopy (TEM) observation showed a special structure just like bamboo. Photoluminescense (PL) spectrum was measured under 488 nm laser excitation from 89 K to 290 K. Three emission peaks were observed at about 580
620 and 740 nm
respectively. It is believed that the emission peaks were concerned with impurity level in the bandgap.