YANG Hai-gui, DAI Zhen-wen, SUN Zhi-wei, SUN Gui-juan. Fluorescent Properties and Lifetimes of <sup>3</sup>P<sub>0</sub> and <sup>1</sup>D<sub>2</sub> Levels in Pr<sup>3+</sup>:ZBLAN Glass[J]. Chinese Journal of Luminescence, 2005,26(1): 42-46
YANG Hai-gui, DAI Zhen-wen, SUN Zhi-wei, SUN Gui-juan. Fluorescent Properties and Lifetimes of <sup>3</sup>P<sub>0</sub> and <sup>1</sup>D<sub>2</sub> Levels in Pr<sup>3+</sup>:ZBLAN Glass[J]. Chinese Journal of Luminescence, 2005,26(1): 42-46DOI:
Fluorescent Properties and Lifetimes of 3P0 and 1D2 Levels in Pr3+:ZBLAN Glass
Heavy-metal fluoride glasses have attracted much attention as host materials due to smaller multi-phonon relaxation rate and high transparence. The optical properties of Pr
3+
ion doped in hosts have also been investigated extensively for its potential application on full-color displays
optical data storage and biomedical instruments. Since detailed spectroscopic studies provide information leading to an assessment of the application of Pr
3+
ions
it is very urgent to explore the optical properties of different levels of Pr
3+
ions in different host materials. The purpose of this paper is to investigate optical characteristics of the
3
P
0
and
1
D
2
levels in Pr
3+
:ZBLAN fluoride glass. Firstly the absorption spectra of Pr
3+
:ZBLAN with two concentrations (110
-3
and 510
-3
in mass fraction were measured by using a spectrophotometer. Then by using time-resolved laser spectroscopy technique
the fluorescence spectra and the lifetimes of the
3
P
0
and
1
D
2
excited states of Pr
3+
ions were investigated under one-photon resonant excitation by a laser beam from the optical parameter oscillator and amplifier system. Experimental fluorescence intensities of the different emission bands were compared with the calculated radiative rates by the Judd-Ofelt theory in literature which indicating that the phenomenological intensity parameters for the Judd-Ofelt theory obtained for Pr
3+
:ZBLAN is reliable. Due to the concentration quenching
the fluorescent intensity of the 110
-3
sample is stronger than that of the 510
-3
sample. However
the lifetimes of the
3
P
0
and
1
D
2
excited states of Pr
3+
ions in ZBLAN glass are not influenced by the concentration. For 110
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Related Author
Jie YANG
Jian-bin ZHAO
Yi-yin LIU
Long YANG
Yang-xiao WANG
Li-guo TANG
He FENG
Fang-fang RUAN
Related Institution
Research Center of Laser Fusion, Chinese Academy of Engineering Physics
Department of Medical Imaging, Hangzhou Medical College
School of Material Science and Engineering, Shanghai University
Shanghai Institute of Ceramics, Chinese Academy of Sciences
Key Laboratory of Yunnan Provincial Higher Education Institution for Optoelectronics Devices Engineering, School of Physics and Astronomy, Yunnan University