STUDY OF THE HALIDE SENSITIZATION EFFECT IN ACETONE CHEMILUMINESCENCE REACTION

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STUDY OF THE HALIDE SENSITIZATION EFFECT IN ACETONE CHEMILUMINESCENCE REACTION

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- STUDY OF THE HALIDE SENSITIZATION EFFECT IN ACETONE CHEMILUMINESCENCE REACTION
- Chinese Journal of Luminescence Vol. 14, Issue 1, Pages: 69-73(1993)
- 作者机构：
  
  中国科学技术大学应用化学系合肥,30026
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Received：05 March 1992，
  
  Published：28 February 1993
- 稿件说明：
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吕小虎, 陆明刚, 赵贵文. 丙酮化学发光反应中卤素离子敏化效应的研究[J]. 发光学报, 1993,14(1): 69-73

Lü Xiaohu, Lu Minggang, Zhao Guiwen. STUDY OF THE HALIDE SENSITIZATION EFFECT IN ACETONE CHEMILUMINESCENCE REACTION[J]. Chinese Journal of Luminescence, 1993,14(1): 69-73
吕小虎, 陆明刚, 赵贵文. 丙酮化学发光反应中卤素离子敏化效应的研究[J]. 发光学报, 1993,14(1): 69-73 DOI：

Lü Xiaohu, Lu Minggang, Zhao Guiwen. STUDY OF THE HALIDE SENSITIZATION EFFECT IN ACETONE CHEMILUMINESCENCE REACTION[J]. Chinese Journal of Luminescence, 1993,14(1): 69-73 DOI：

摘要

本文报导了丙酮化学发光反应中卤素离子的敏化效应

对其敏化机理进行了探讨

并研究卤素离子敏化效应的分析应用。

Abstract

In basic medium

acetone can react with CIO

and H

to produce chemiluminescence (CL) emission. The halide ions were found to sensitize the acetone CL reaction. The mechanism of the halide sensitization effect has been briefly discussed. Based on this effect

a novel CL method for the determination of iodide ion was proposed. The experimental results illustrate that the detection limit is 2.0×10

-11

g/ml I

and the linear range is 4.0×l0

-1

g/ml to 3.0×10

-7

g/ml. The effect of some foreign ions was also studied.

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