Xiao Jinglin, Sun Baoquan. SELF-TRAPPING CONDITION OF SURFACE EXCITON IN POLYATOMIC POLAR CRYSTALS[J]. Chinese Journal of Luminescence, 1992,13(4): 323-332
Xiao Jinglin, Sun Baoquan. SELF-TRAPPING CONDITION OF SURFACE EXCITON IN POLYATOMIC POLAR CRYSTALS[J]. Chinese Journal of Luminescence, 1992,13(4): 323-332DOI:
SELF-TRAPPING CONDITION OF SURFACE EXCITON IN POLYATOMIC POLAR CRYSTALS
The properties of exciton in the surface layer of crystals influence the optical properties of the crystals very remarkably. In recent years
many scholars
[1-2]
discussed the properties of the surface exciton. Most polar crystals are diatomic. In these crystals there is one mode of the longitudinal optical (LO) phonon. However
a large number of polar crystals
with several atoms per unit cell
have more than one LO phonon branch. In recent years the polar on problem with many LO phonon branches has been studied
[3-4]
. However
the exciton in polyatomic polar crystals has not been investigated so far. The ground state energy of a weak
intermediate and strong coupling exciton in polyatomic polar crystals has been obtained by means of perturbation and linear -combination-operator method by one of authors
[5-6]
. Recently the effective Hamiltonian of the surface exciton in polyatomic polar crystals was derived by using perturbation method by author
[7]
. When we consider the interaction between phonons of different wave vector in the recoil process
the influence on effective potential between the electron and the hole
the self-trapping energy and the self-trapping condition are discussed.The Hamiltonian of a polyatomic surface exciton-phonon system is