Yu Yingning, Sun Xiaozhong, Wang Wenyun. DIRECT SPECTROSCOPIC OBSERVATION OF NEAR-INFRARED PHOSPHORESCENCE OF O<sub>2</sub>(<sup>1</sup>△<sub>g</sub>)[J]. Chinese Journal of Luminescence, 1990,11(1): 55-60
Yu Yingning, Sun Xiaozhong, Wang Wenyun. DIRECT SPECTROSCOPIC OBSERVATION OF NEAR-INFRARED PHOSPHORESCENCE OF O<sub>2</sub>(<sup>1</sup>△<sub>g</sub>)[J]. Chinese Journal of Luminescence, 1990,11(1): 55-60DOI:
DIRECT SPECTROSCOPIC OBSERVATION OF NEAR-INFRARED PHOSPHORESCENCE OF O2(1△g)
The chemicd and kinetic properties of singlet molecular oxygen in liquid phase have attracted much attention of chemists and biochemists owing to its involvement in many chemical and biological processes. This transient entity
however
had evaded direct observation until a decade ago when the 1270nm luminescence from the forbidden tiansition
1
△
g
O
2
(v=O)→
3
∑
g
-
O
2
(v=O) was detected via photosensitization in solution. The success of this measurement was achieved by using germanium photodiode (with much highei sensitivity in the infrared legion than in the visible region in contrast to photomultipliei tubes) coupled to fast
high-gain amplifiers. However
Ge photodiodes satisfying the measurement of ultra-weak 1270 nm band of O
2
(
1
△
g
) are not yet available in our country. Based on the results of Krasnovsky in direct observation of singlet oxygen emission at 1270 nm with red-sensitive PMT
it is of interest to see the feasibility to detect the (1
0) transition emission of O
2
(
1
△
g
) at 1070 nm by using PMT of S-1 photocathode with a spectral response ranging from 300 to 1150 nm
and a successful demonstration of this proposed approach is described in this paper.