Ye Jianping, Yu Qun, Cao Hong, Shou Hanscn. LUMINESCENCE OF TERBIUM (Ⅱ)-SALICYLATE COMPLEX AND ITS ENERGY TRANSFER TO EUROPIUM(Ⅲ)[J]. Chinese Journal of Luminescence, 1989,10(4): 325-331
Ye Jianping, Yu Qun, Cao Hong, Shou Hanscn. LUMINESCENCE OF TERBIUM (Ⅱ)-SALICYLATE COMPLEX AND ITS ENERGY TRANSFER TO EUROPIUM(Ⅲ)[J]. Chinese Journal of Luminescence, 1989,10(4): 325-331DOI:
LUMINESCENCE OF TERBIUM (Ⅱ)-SALICYLATE COMPLEX AND ITS ENERGY TRANSFER TO EUROPIUM(Ⅲ)
The formation and luminescence properties of the complex of terbium ion (Tb
3+
)-salicylates (methyl salicylate MS
and phenyl salicylate PS) and the energy transfer processes from the complex to europium ion (Eu
3+
) have been investigated by use of the steady state and transient state time-resolved emission spectroscopy.From the fluorecence spectra and lifetime data of the MP system (Table 1)
it can be seen that
with the increase of Tb
3+
concentration
the fluorescence intensity of the MP decreases and the characteristic emission of Tb
3+
ions increases.Plots of F
0
/F against the concentration of Tb
3+
ions satisfy the Stern-Volmer equation.But the fluorescence lifetime remains constant
τ
0
/τ≈1. this is a typical static quenching process
[4]
. Absorption changes are also observed in the absorption spectra and the absorption peaks of complex appear at longer wavelength than those of MS and PS do.We can conclude from the study that Tb
3+
ions form steady complex in ground state with MP
MS by certain proportion and transfer the absorption energy effectively to center Tb
3+
ions. The terbium luminescence intensity is increased by many times in the complex than that in the studied systems.